Thermal Desorption Particle Beam Mass Spectrometer and Thermal-Denuder + AMS Spectral Database

This page is a compilation of published spectra and thermal desorption profiles obtained with the UC-Riverside TDPBMS. Spectra with thermal-denuder + AMS will also be added later. The development of the thermal-denuder + AMS technique and of this database have been supported by EPA STAR grant R831080 to UC-Riverside, CU-Boulder, and Aerodyne Research.

These spectra have been made available to the entire community. By using these spectra you agree to make appropriate citations of the papers referenced. Please honor this request so that the spectra can continue to be available to everyone. Also please cite this database as "Ziemann, P. and Faulhaber, A. TDPBMS Spectral Database. URL:http://cires.colorado.edu/jimenez-group/TDPBMSsd/".

If you have spectra you'd like added to the database, please send them to Michael Lechner, Your comments are also welcome!

Spectra are divided into several categories with respective ID labels:

Note that replicates of spectra are of great interest. As in the NIST or Wiley databases, replicates allow the user to identify differences that may be due to impurities, different experimental conditions, instrumental differences, etc.

Database Version 1.2 with 16 sets (spectrum + thermograms) available.

If you would like to download all of the spectrum contained in this database please Click Here.

Laboratory Spectra--SOA--Alkene

Spectra ID
Source
Group
Instrument
EI Energy
Vaporizer Temp (oC)
Citation
Fig #
Comments
Thermal Desorption Profile
Thermodenuder Vaporization Profile
Real Time Mass Spectrum
ZL_SOA_ENE_001 1-Tetradecene + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Thermodenuder Profile is Calculated
ZL_SOA_ENE_001_1Tetradecene_OH_TPTD.itx

ZL_SOA_ENE_001_1Tetradecene_OH_TD.itx

ZL_SOA_ENE_001_1Tetradecene_OH_CPS.itx
ZL_SOA_ENE_002 1-Tetradecene + NO3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Gong, H., et al.,J. Phys. Chem. A, 2005, 109, pgs. 4312-4324 RTMS: Fig. 3
TDP: Fig. 4
Thermodenuder Profile is Calculated
ZL_SOA_ENE_002_1Tetradecene_NO3_TPTD.itx

ZL_SOA_ENE_002_1Tetradecene_NO3_TD.itx

ZL_SOA_ENE_002_1Tetradecene_NO3_CPS.itx
ZL_SOA_ENE_003 Cyclododecene + NO3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Thermodenuder Profile is Calculated
ZL_SOA_ENE_003_Cyclododecene_NO3_TPTD.itx

ZL_SOA_ENE_003_Cyclododecene_NO3_TD.itx

ZL_SOA_ENE_003_Cyclododecene_NO3_CPS.itx
ZL_SOA_ENE_004 β-Pinene + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Thermodenuder Profile is Calculated
ZL_SOA_ENE_004_bPinene_OH_TPTD.itx

ZL_SOA_ENE_004_bPinene_OH_TD.itx

ZL_SOA_ENE_004_bPinene_OH_CPS.itx
ZL_SOA_ENE_005 β-Pinene + NO3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Thermodenuder Profile is Calculated
ZL_SOA_ENE_005_bPinene_NO3_TPTD.itx

ZL_SOA_ENE_005_bPinene_NO3_TD.itx

ZL_SOA_ENE_005_bPinene_NO3_CPS.itx

Laboratory Spectra--SOA--Alkane

Spectra ID
Source
Group
Instrument
EI Energy
Vaporizer Temp (oC)
Citation
Fig #
Comments
Thermal Desorption Profile
Thermodenuder Vaporization Profile
Real Time Mass Spectrum
ZL_SOA_ANE_001 2,6,10-Trimethyldodecane + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Lim, Y.B., et al., ES&T, 2005, 39, pgs. 9229-9236   Thermodenuder profile is calculated
ZL_SOA_ANE_001_2,6,10Trimethyldodecane_OH_TPTD.itx

ZL_SOA_ANE_001_2,6,10Trimethyldodecane_OH_TD.itx

ZL_SOA_ANE_001_2,6,10Trimethyldodecane_OH_CPS.itx
ZL_SOA_ANE_002 Pentadecane + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Lim, Y.B., et al., ES&T, 2005, 39, pgs. 9229-9236 RTMS: Fig. 2
TDP: Fig. 3
Thermodenuder profile is calculated
ZL_SOA_ANE_002_Pentadecane_OH_TPTD.itx

ZL_SOA_ANE_002_Pentadecane_OH_TD.itx

ZL_SOA_ANE_002_Pentadecane_OH_CPS.itx
ZL_SOA_ANE_003 Undecane + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Lim, Y.B., et al., ES&T, 2005, 39, pgs. 9229-9236   Thermodenuder profile is calculated
ZL_SOA_ANE_003_Undecane_OH_TPTD.itx

ZL_SOA_ANE_003_Undecane_OH_TD.itx

ZL_SOA_ANE_003_Undecane_OH_CPS.itx
ZL_SOA_ANE_004 Cyclopentadecane + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Lim, Y.B., et al., ES&T, 2005, 39, pgs. 9229-9236   Thermodenuder profile is calculated
ZL_SOA_ANE_004_Cyclopentadecane_OH_TPTD.itx

ZL_SOA_ANE_004_Cyclopentadecane_OH_TD.itx

ZL_SOA_ANE_004_Cyclopentadecane_OH_CPS.itx
ZL_SOA_ANE_005 Decylcyclohexane + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Lim, Y.B., et al., ES&T, 2005, 39, pgs. 9229-9236   Thermodenuder profile is calculated
ZL_SOA_ANE_005_Decylcyclohexane_OH_TPTD.itx

ZL_SOA_ANE_005_Decylcyclohexane_OH_TD.itx

ZL_SOA_ANE_005_Decylcyclohexane_OH_CPS.itx

Laboratory Spectra--SOA--Aromatic

Spectra ID
Source
Group
Instrument
EI Energy
Vaporizer Temp (oC)
Citation
Fig #
Comments
Thermal Desorption Profile
Thermodenuder Vaporization Profile
Real Time Mass Spectrum
ZL_SOA_ARO_001 Toluene + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Desorption profile is calculated
ZL_SOA_ARO_Toluene_OH_TPTD.itx

ZL_SOA_ARO_Toluene_OH_TD.itx

ZL_SOA_ARO_Toluene_OH_CPS.itx
ZL_SOA_ARO_002 m-Xylene + OH Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
    Desorption profile is calculated
ZL_SOA_ARO_002_mXylene_OH_TPTD.itx

ZL_SOA_ARO_002_mXylene_OH_TD.itx

ZL_SOA_ARO_002_mXylene_OH_CPS.itx

Laboratory Spectra--SOA--Monoterpene

Spectra ID
Source
Group
Instrument
EI Energy
Vaporizer Temp (oC)
Citation
Fig #
Comments
Thermal Desorption Profile
Thermodenuder Vaporization Profile
Real Time Mass Spectrum
ZL_SOA_MON_001 α-Pinene + O3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Docherty, K.S., et al., ES&T, 2005, 39, pgs. 4049-4059 RTMS: Fig. 2
TDP: Fig. 4
Thermodenuder profile is calculated
ZL_SOA_MON_001_aPinene_O3_TPTD.itx

ZL_SOA_MON_001_aPinene_O3_TD.itx

ZL_SOA_MON_001_aPinene_O3_CPS.itx
ZL_SOA_MON_002 β-Pinene + O3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Docherty, K.S., et al., ES&T, 2005, 39, pgs. 4049-4059 RTMS: Fig. 2
Thermodenuder profile is calculated
ZL_SOA_MON_002_bPinene_O3_TPTD.itx

ZL_SOA_MON_002_bPinene_O3_TD.itx

ZL_SOA_MON_002_bPinene_O3_CPS.itx
ZL_SOA_MON_003 Sabinene + O3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Docherty, K.S., et al., ES&T, 2005, 39, pgs. 4049-4059 RTMS: Fig. 2
TDP: Fig. 4
Thermodenuder profile is calculated
ZL_SOA_MON_003_Sabinene_O3_TPTD.itx

ZL_SOA_MON_003_Sabinene_O3_TD.itx

ZL_SOA_MON_003_Sabinene_O3_CPS.itx
ZL_SOA_MON_004 3-Carene + O3 Paul Ziemann
University of California-Riverside
TDPBMS 70ev 160
Docherty, K.S., et al., ES&T, 2005, 39, pgs. 4049-4059 RTMS: Fig. 2
TDP: Fig. 4
Thermodenuder profile is calculated
ZL_SOA_MON_004_3Carene_O3_TPTD.itx

ZL_SOA_MON_004_3Carene_O3_TD.itx

ZL_SOA_MON_004_3Carene_O3_CPS.itx

Definition of Abbreviations
TDP - Thermal Desorption Profile
RTMS - Real Time Mass Spectrum


This page is maintained by Michael Lechner of the Jimenez Group at the University of Colorado.

This page was last updated on January 11, 2008