Evidence for midwinter chemical ozone destruction over Antarctica
H. Vömel
Department of Physics, University of Colorado, Boulder
D. J. Hofmann, S. J. Oltmans, and J. M. Harris
NOAA, Climate Monitoring and Diagnostics Laboratory, Boulder
Abstract. Two ozone profiles on June 15 and June
19, obtained over McMurdo, Antarctica, showed a strong depletion in stratospheric
ozone, and a simultaneous profile of water vapor on June 19 showed the
first clear signs of dehydration. The observation of Polar Stratospheric
Clouds (PSCs) beginning with the first sounding showing ozone depletion,
the indication of rehydration layers, which could be a sign for recent
dehydration, and trajectory calculations indicate that the observed low
ozone was not the result of transport from lower latitudes. During this
time the vortex was strongly distorted, transporting PSC processed air
well into sunlit latitudes where photochemical ozone destruction may have
occurred. The correlation of ozone depletion and dehydration indicates
that water ice PSCs provided the dominant surface for chlorine activation.
An analysis of the time when the observed air masses could have formed
type II PSCs for the first time limits the time scale for the observed
ozone destruction to about 4 days.