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CIRES Graduate Student Research Award ProgramCIRES Graduate Student Research Award ProgramCIRES supports a Graduate Student Research Award program to promote student scholarship and research excellence. The goal of the program is to recognize the scholarship and merit of CIRES' outstanding graduate students. Any current Ph.D. student that is formally supervised by a CIRES Fellow or CIRES Researcher is eligible for this one-time award opportunity. Prospective graduate students are not eligible to apply. The 2022 competition opens January 28, 2022. Applications are due February 21, 2022. »
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CIRES Town Hall
CIRES Town HallPlease join CIRES Director Waleed Abdalati for another CIRES Town Hall on Tuesday, February 1 for both CU Boulder and NOAA-based employees. The agenda this week includes: the CIRES DEI strategic plan and start the CIRES-wide comment period.
Join Zoom Meeting: https://cuboulder.zoom.us/j/93081058086 Meeting ID: 930 8105 8086 One tap mobile +12532158782,,93081058086# US (Tacoma) +13462487799,,93081058086# US (Houston)
Dial by your location +1 253 215 8782 US (Tacoma) +1 346 248 7799 US (Houston) +1 669 900 6833 US (San Jose) +1 301 715 8592 US (Washington DC) +1 312 626 6799 US (Chicago) +1 646 558 8656 US (New York) Meeting ID: 930 8105 8086 Find your local number: https://cuboulder.zoom.us/u/abG5vTWm3g DateTuesday, February 1, 2022 9:00 am to 10:00 am Host
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2022-02-01 Earth Lab EDS Seminar Series
Earth Lab EDS Seminar SeriesAre you looking to broaden your perspectives in Earth and environmental data science? Are you excited to collaborate with others and hear about new developments in this area? Topics must be about using *big data* to advance knowledge of the dynamics and interactions of the Earth system, towards actionable insights and tools Starting Spring 2022, Earth Lab will be hosting a regular weekly 50-min seminar series on topics related to Environmental Data Science (EDS) that uses big data to advance knowledge of the dynamics and interactions of the Earth systems, towards actionable insights and tools. These weekly sessions are intended to inspire collaboraitons and creative problem solving using data and analytics for a broad range of environmental science topics. Each week will be led by someone and can take on many forms: data jams, ractice conference talks (15 min) w/ Q&A, paper Discussions, brainstorming, 30 min lecture, other. Purpose: To reignite collaborations by inspiring creative problem solving by sharing the many interesting projects and work that Earth Lab and affiliates have been doing to advance the use of data for environmental challenges. This week's topic: Forest responses to linked disturbance in Australia Speaker: Anna Spiers - Department of Ecology & Evolutionary Biology Visit our website for more details. DateTuesday, February 1, 2022 11:00 am to 12:00 pm Host
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2022-02-01 |
ESOC Coffee Hour
ESOC Coffee HourESOC virtual coffee hour occurs weekly from 9-10am on Wednesdays. We will be meeting remotely on Zoom. Please email Claire Waugh (waughc@colorado.edu) for information. ESOC researchers, post-docs and graduate students gather for conversation and to discuss research. Occasional guest speakers are invited to give short presentations on topics of interest. This week Fangfang Yao, CIRES/ESOC Post-Doctoral Researcher, will give a talk “Understanding lake level variability from regional to global scales: trends, drivers and impacts”. DateWednesday, February 2, 2022 9:00 am to 10:00 am Host
contactClaire Waugh; waughc@colorado.edu 2022-02-02 |
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CIRES Graduate Student Research Award ProgramCIRES Graduate Student Research Award ProgramCIRES supports a Graduate Student Research Award program to promote student scholarship and research excellence. The goal of the program is to recognize the scholarship and merit of CIRES' outstanding graduate students. Any current Ph.D. student that is formally supervised by a CIRES Fellow or CIRES Researcher is eligible for this one-time award opportunity. Prospective graduate students are not eligible to apply. The 2022 competition opens January 28, 2022. Applications are due February 21, 2022. »
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Earth Lab EDS Seminar Series
Earth Lab EDS Seminar SeriesAre you looking to broaden your perspectives in Earth and environmental data science? Are you excited to collaborate with others and hear about new developments in this area? Topics must be about using *big data* to advance knowledge of the dynamics and interactions of the Earth system, towards actionable insights and tools Starting Spring 2022, Earth Lab will be hosting a regular weekly 50-min seminar series on topics related to Environmental Data Science (EDS) that uses big data to advance knowledge of the dynamics and interactions of the Earth systems, towards actionable insights and tools. These weekly sessions are intended to inspire collaboraitons and creative problem solving using data and analytics for a broad range of environmental science topics. Each week will be led by someone and can take on many forms: data jams, ractice conference talks (15 min) w/ Q&A, paper Discussions, brainstorming, 30 min lecture, other. Purpose: To reignite collaborations by inspiring creative problem solving by sharing the many interesting projects and work that Earth Lab and affiliates have been doing to advance the use of data for environmental challenges. This week's topic: Human causes and impacts of Fire in the Western US Speaker: Phil Higueria - University of Montana Visit our website for more details. DateTuesday, February 8, 2022 11:00 am to 12:00 pm LinkHost
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Resources2022-02-08 |
ESOC Coffee Hour
ESOC Coffee HourESOC virtual coffee hour occurs weekly from 9-10am on Wednesdays. We will be meeting remotely on Zoom. Please email Claire Waugh (waughc@colorado.edu) for information. ESOC researchers, post-docs and graduate students gather for conversation and to discuss research. Occasional guest speakers are invited to give short presentations on topics of interest. DateWednesday, February 9, 2022 9:00 am to 10:00 am Host
contactClaire Waugh; waughc@colorado.edu 2022-02-09 |
NC CASC Webinar Series Webinar: Developing Climate Information for US Fish and Wildlife Service Species Status Assessments Using the Climate Toolbox
NC CASC Webinar Series Webinar: Developing Climate Information for US Fish and Wildlife Service Species Status Assessments Using the Climate Toolbox![]() Please join us for the NC CASC Webinar Series Webinar on Thursday, February 10, 2022, 11a -12p MST: "Developing Climate Information for US Fish and Wildlife Service Species Status Assessments Using the Climate Toolbox" Presented by: Katherine Hegewisch, University of California Merced John Guinotte, U.S. Fish and Wildlife Service Alexandra Kasdin, U.S. Fish and Wildlife Service Registration link: Please register in advance for this meeting: https://cuboulder.zoom.us/meeting/register/tJYocuGrqD0rGNHZ0LQcsqwe2067uK-iJOlx After registering, you will receive a confirmation email containing information about how to join the meeting. Abstract: Field biologists from the U.S. Fish and Wildlife Service develop climate information for species status assessments of potentially endangered species using data from ClimateToolbox.org. In this webinar, we will discuss the data needs for these assessments and will provide an overview of the data and tools in the Climate Toolbox with specific examples of how biologists currently utilize the Toolbox for assessments. About the speakers: Katherine Hegewisch is a project scientist at the University of California Merced where she works as a climate data provider, analyst and web tool developer. She is the developer of the Climate Toolbox, a series of web tools for visualizing climate data. She received her PhD in physics from Washington State University in 2010. John Guinotte is a spatial ecologist with the US Fish and Wildlife Service (FWS), in its Ecological Services Program, based out of the legacy region 6 office in Lakewood Colorado. John assists FWS field offices across regions 5 and 7 with analytical, geospatial and statistical needs for listing or delisting species under the Endangered Species Act’s Species Status Assessments. In addition to informing listing decisions, John’s work supports habitat conservation plans, recovery, critical habitat, climate vulnerability and mitigation. John has PhD in Tropical Environmental Studies and Geography from James Cook University in Australia. Alex Kasdin is a Species Assessment Team Project Manager with the Ecological Services Program of the U.S. Fish and Wildlife Service; she works out of the Regional Office in Lakewood, Colorado. She leads teams of biological experts crafting Species Status Assessments to inform classification decisions under the Endangered Species Act. She also helps decision-makers apply the standards in the Act to determine if species warrant listing. Alex has a Bachelor’s degree in Ecology and Evolutionary Biology and a Master’s in Public Affairs, both from Princeton University.
Previous NC CASC webinar recordings: https://nccasc.colorado.edu/webinars DateThursday, February 10, 2022 11:00 am to 12:00 pm Host
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2022-02-10 |
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CIRES Graduate Student Research Award ProgramCIRES Graduate Student Research Award ProgramCIRES supports a Graduate Student Research Award program to promote student scholarship and research excellence. The goal of the program is to recognize the scholarship and merit of CIRES' outstanding graduate students. Any current Ph.D. student that is formally supervised by a CIRES Fellow or CIRES Researcher is eligible for this one-time award opportunity. Prospective graduate students are not eligible to apply. The 2022 competition opens January 28, 2022. Applications are due February 21, 2022. »
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Innovative Research Program
Innovative Research ProgramThe Innovative Research Program is designed to stimulate a creative research environment within CIRES and to encourage synergy between disciplines and research colleagues. The intent is to support small research efforts that can quickly provide concept viability or rule out further consideration. The program encourages novel, unconventional or fundamental research that might otherwise be difficult to fund. Funded projects are inventive, sometimes opportunistic, and do not necessarily have an immediate practical application or guarantee of success. This program supports pilot or exploratory studies, which may provide rapid results. Activities are not tightly restricted and can range from instrument development, lab testing, and field observations to model development, evaluation, and application. The 2022 IRP competition opens February 14, 2022. Applications will be due March 28, 2022. Submit your proposal online. You must have a CIRES login and password to access the online application. January 2022 update: CIRES is instituting a "Rapid IRP" to provide funds for research activities that are time-sensitive and urgent. Potential CIRES proposers should see the email or reach out to the Associate Director for Science for more information. »
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Atmospheric Chemistry Program Seminar
Atmospheric Chemistry Program SeminarLonger term aging of organic aerosol: photobleaching and chemical transformations Rachel O'Brien, "Organic aerosol particles can influence the climate through either directly absorbing or scattering solar radiation or by acting as nuclei for cloud droplets. Some aerosol particles are dominantly scattering while others contain organic molecules that can absorb solar radiation in the visible region, termed brown carbon (BrC). We still have large uncertainties in the magnitude of these climate effects and a better understanding of the removal rates for the particle mass and absorption properties (i.e. color) is needed. One removal process is photolysis, where absorption of solar radiation leads to fragmentation of the organic molecules and the loss of particle mass and/or color. However, the photolysis rates and the overall extent of mass that can be removed via direct photolysis in laboratory experiments does not match what is used in models and often differs from ambient measurements. In this talk, I will combine results from work in our lab looking at photolysis of biogenic secondary organic aerosol as well as BrC from biomass burning organic aerosol to evaluate gaps in our ability to predict the observed ambient removal rates. By probing complex mixtures from recent biomass burning experiments (e.g. FIREX samples), I will demonstrate that our current measured rates in the laboratory are overestimated and that a slower photolysis rate, as well as a potential gas-phase oxidation rate, should be used to predict the role of photolysis on organic aerosol lifetime in the atmosphere." DateMonday, February 14, 2022 12:15 pm Host
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contactanne.handschy@colorado.edu 2022-02-14 |
Earth Lab EDS Seminar
Earth Lab EDS SeminarCorrection, see here for Feb 22 seminar: https://cires.colorado.edu/events/earth-lab-eds-seminar-0
Are you looking to broaden your perspectives in Earth and environmental data science? Are you excited to collaborate with others and hear about new developments in this area? Topics must be about using *big data* to advance knowledge of the dynamics and interactions of the Earth system, towards actionable insights and tools Starting Spring 2022, Earth Lab will be hosting a regular weekly 50-min seminar series on topics related to Environmental Data Science (EDS) that uses big data to advance knowledge of the dynamics and interactions of the Earth systems, towards actionable insights and tools. These weekly sessions are intended to inspire collaboraitons and creative problem solving using data and analytics for a broad range of environmental science topics. Each week will be led by someone and can take on many forms: data jams, ractice conference talks (15 min) w/ Q&A, paper Discussions, brainstorming, 30 min lecture, other. Purpose: To reignite collaborations by inspiring creative problem solving by sharing the many interesting projects and work that Earth Lab and affiliates have been doing to advance the use of data for environmental challenges. This week's topic: Assisted Migration Analytics to Rescue Populations from Extinction Speaker: Ty Tuff - CIRES Earth Lab Visit our website for more details. DateTuesday, February 15, 2022 11:00 am Host
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2022-02-15 |
NSIDC Cryosphere Seminar
NSIDC Cryosphere Seminar![]() High mountain biodiversity under climate change: progress, challenges, and promise by Dr. Scott Hotaling Abstract: Climate change is dramatically altering mountain ecosystems worldwide. In high-elevation regions, perhaps the most consequential change is the rapid recession of glaciers and perennial snowfields. How a changing cryosphere will impact biodiversity, particularly in glacier and meltwater-driven habitats, is poorly known. In this seminar, I will integrate community ecology, ecophysiology, and molecular tools to give a broad overview of the existing biodiversity in high mountain habitats, its potential fate under climate change, and the evidence for in situ refugia to buffer these changes. Bio: Scott Hotaling is currently a postdoc in the School of Biological Sciences at Washington State University but in Summer 2022, he’ll be starting a new lab at Utah State University in the Dept. of Watershed Sciences. He received a PhD in 2017 from the University of Kentucky (Advisor: David Weisrock) and has a BS from North Carolina State University (2011). In 2015, he co-founded the Teton Alpine Stream Research project which is dedicated to using long-term ecological monitoring to quantify how mountain aquatic ecosystems are changing. He is also a big fan of Twitter (@MtnScience).
TO JOIN BY ZOOM: From a computer: https://cuboulder.zoom.us/j/5409618610 Or iPhone one-tap : US: +16465588656,,5409618610# Or Telephone: Dial(for higher quality, dial a number based on your current location): US: +1 646 558 8656 Meeting ID: 540 961 8610 International numbers available: https://zoom.us/u/MNl8z DateWednesday, February 16, 2022 11:00 am to 12:00 pm Mountain LinkHost
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Resourcescontact2022-02-16 ESOC Coffee Hour
ESOC Coffee HourESOC virtual coffee hour occurs weekly from 9-10am on Wednesdays. We will be meeting remotely on Zoom. Please email Claire Waugh (waughc@colorado.edu) for information. ESOC researchers, post-docs and graduate students gather for conversation and to discuss research. Occasional guest speakers are invited to give short presentations on topics of interest. DateWednesday, February 16, 2022 9:00 am to 10:00 am Host
contactClaire Waugh; waughc@colorado.edu 2022-02-16 |
Building your mentor network
Building your mentor networkPlease join CGA members and Christine Wiedinmyer for our first Hidden Curricuculm seminar in the series to discuss building your network of mentors! The Hidden Curriculum seminars were developed by Amanda Donaldson, Galen Gorski, Colleen Murphy, Jenny Pensky, Adam Price, Christina Richardson, Araceli Serrano, and Margaret Zimmer* because much of the graduate school experience is focused on tangible and formal skill development surrounding research and teaching. These seminars focuses on the informal “hidden curriculum” in graduate school that can complement formal student learning to help individuals lead successful research careers. The first seminar of this series will focus on how to build your network of mentors, lead by CIRES' own, Christine Wiedinmyer. She will discuss how to find and pick mentors in order to build the best supportive network. Please join us on Thursday February 17th @12:30 - 2 pm on zoom to hear some tips and ask your own questions. RSVP here by Wednesday at 11:59 pm MST in order to receive the zoom link on Thursday morning. * Source:
Important resources mentioned during the event: Writing support + Professional development opportunities through the Graduate School: https://www.colorado.edu/graduateschool/professional-development-community CU Student + postdoctoral services: https://ciresecguide.colorado.edu/cu-services National Center for Faculty Development & Diversity (activate your membership here): https://www.facultydiversity.org/institutions/university-of-colorado-boulder Graduate student process therapy groups through CU (included in CU Gold plan): https://www.colorado.edu/counseling/services/process-therapy-groups Faculty & staff counseling services: https://www.colorado.edu/hr/faculty-staff-assistance-program Confidential reporting services: Cireshr@colorado.edu & https://www.colorado.edu/ombuds/ Graduate student/advisor mentoring agreement: https://www.colorado.edu/engineering-facultystaff/sites/default/files/attached-files/advising_agreement_final_final.pdf DateThursday, February 17, 2022 12:30 pm to 2:00 pm Host
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CIRES Graduate Student Research Award ProgramCIRES Graduate Student Research Award ProgramCIRES supports a Graduate Student Research Award program to promote student scholarship and research excellence. The goal of the program is to recognize the scholarship and merit of CIRES' outstanding graduate students. Any current Ph.D. student that is formally supervised by a CIRES Fellow or CIRES Researcher is eligible for this one-time award opportunity. Prospective graduate students are not eligible to apply. The 2022 competition opens January 28, 2022. Applications are due February 21, 2022. |
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Innovative Research ProgramInnovative Research ProgramThe Innovative Research Program is designed to stimulate a creative research environment within CIRES and to encourage synergy between disciplines and research colleagues. The intent is to support small research efforts that can quickly provide concept viability or rule out further consideration. The program encourages novel, unconventional or fundamental research that might otherwise be difficult to fund. Funded projects are inventive, sometimes opportunistic, and do not necessarily have an immediate practical application or guarantee of success. This program supports pilot or exploratory studies, which may provide rapid results. Activities are not tightly restricted and can range from instrument development, lab testing, and field observations to model development, evaluation, and application. The 2022 IRP competition opens February 14, 2022. Applications will be due March 28, 2022. Submit your proposal online. You must have a CIRES login and password to access the online application. January 2022 update: CIRES is instituting a "Rapid IRP" to provide funds for research activities that are time-sensitive and urgent. Potential CIRES proposers should see the email or reach out to the Associate Director for Science for more information. »
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Atmospheric Chemistry Program Seminar
Atmospheric Chemistry Program SeminarAn Investigation of Carboxylic Acid Chemistry in Indoor and Outdoor Environments Anna Ziola, ANYL 3rd year, "Carboxylic acids are prominent organic molecules in indoor and outdoor environments and also have chemical properties that make them useful probes for investigating the chemistry of indoor and outdoor air. Even though the average person spends nearly 90% of their lifetime indoors, we know very little about the processes that impact volatile organic compounds (VOCs) in indoor environments, where there are a variety of surfaces that VOCs can interact with. To understand the role of wood surfaces, we have used an iodide chemical ionization mass spectrometer (I-CIMS) and an attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrometer along with a model to quantify and better understand how carboxylic acids interact with a variety of wood species and varnishes. These experiments have provided parameters for use in models and shown that the behavior of carboxylic acid VOCs indoors relies more on the identity of the varnish and less on the identity of the wood species. We have also taken advantage of the chemical properties of carboxylic acids to study the oxidation of alkenes in low NOx environments. According to data from CalNex in 2010 and LAAQS in 2020, the concentration of mid-day NO, a prominent component in VOC oxidation mechanisms, has decreased by about 75% in Los Angeles in the past decade. There have been many studies on the oxidation of VOCs in high NOx environments, but far fewer in the absence of NOx. To gather more knowledge about low NOx chemistry, we reacted 6-heptenoic acid, a C7 1-alkene with a terminal carboxylic acid group, with OH radicals in an environmental chamber while using an I-CIMS to identify and quantify gas-phase products. We also collected aerosol particles on filters, derivatized the carboxylic acid groups, and identified and quantified the products using high performance liquid chromatography (HPLC) in tandem with an electrospray ionization mass spectrometer (ESI-MS). Therefore, by taking advantage of carboxylic acid properties, we have been able to better understand their interactions with indoor surfaces and gain insights into the oxidation of alkenes under low NOx conditions." DateMonday, February 21, 2022 12:15 pm Host
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contactanne.handschy@colorado.edu 2022-02-21 |
Earth Lab EDS Seminar
Earth Lab EDS SeminarAre you looking to broaden your perspectives in Earth and environmental data science? Are you excited to collaborate with others and hear about new developments in this area? Topics must be about using *big data* to advance knowledge of the dynamics and interactions of the Earth system, towards actionable insights and tools Starting Spring 2022, Earth Lab will be hosting a regular weekly 50-min seminar series on topics related to Environmental Data Science (EDS) that uses big data to advance knowledge of the dynamics and interactions of the Earth systems, towards actionable insights and tools. These weekly sessions are intended to inspire collaboraitons and creative problem solving using data and analytics for a broad range of environmental science topics. Each week will be led by someone and can take on many forms: data jams, ractice conference talks (15 min) w/ Q&A, paper Discussions, brainstorming, 30 min lecture, other. Purpose: To reignite collaborations by inspiring creative problem solving by sharing the many interesting projects and work that Earth Lab and affiliates have been doing to advance the use of data for environmental challenges. This week's topic: Joint Species Distribution Modeling Speaker: Adam Mahood - CIRES Earth Lab Visit our website for more details. DateTuesday, February 22, 2022 11:00 am to 12:00 pm Host
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2022-02-22 |
ESOC Coffee Hour
ESOC Coffee HourESOC virtual coffee hour occurs weekly from 9-10am on Wednesdays. We will be meeting remotely on Zoom. Please email Claire Waugh (waughc@colorado.edu) for information. ESOC researchers, post-docs and graduate students gather for conversation and to discuss research. Occasional guest speakers are invited to give short presentations on topics of interest. DateWednesday, February 23, 2022 9:00 am to 10:00 am Host
contactClaire Waugh; waughc@colorado.edu 2022-02-23 |
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CIRES Members' Council Meeting
CIRES Members' Council MeetingPlease join the CMC for their monthly meeting. Join by Google Meet or phone: (US) +1 470-771-3037 (PIN: 191011736) DateFriday, February 25, 2022 9:00 am to 10:30 am LinkHost
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ResourcescontactAaron Sweeney 2022-02-25 |
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Innovative Research ProgramInnovative Research ProgramThe Innovative Research Program is designed to stimulate a creative research environment within CIRES and to encourage synergy between disciplines and research colleagues. The intent is to support small research efforts that can quickly provide concept viability or rule out further consideration. The program encourages novel, unconventional or fundamental research that might otherwise be difficult to fund. Funded projects are inventive, sometimes opportunistic, and do not necessarily have an immediate practical application or guarantee of success. This program supports pilot or exploratory studies, which may provide rapid results. Activities are not tightly restricted and can range from instrument development, lab testing, and field observations to model development, evaluation, and application. The 2022 IRP competition opens February 14, 2022. Applications will be due March 28, 2022. Submit your proposal online. You must have a CIRES login and password to access the online application. January 2022 update: CIRES is instituting a "Rapid IRP" to provide funds for research activities that are time-sensitive and urgent. Potential CIRES proposers should see the email or reach out to the Associate Director for Science for more information. »
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Supervisor Training Series: Best Practices for ALL Supervisors
Supervisor Training Series: Best Practices for ALL SupervisorsPlease join CIRES HR for a Supervisors Best Practices training seminar on February 28 at 10 am. If you are a supervisor, please attend, as this training is relevant for all CIRES supervisors regardless of how long you have been a supervisor. Many things have evolved over the years on hiring, career development, and annual evaluations, leave reporting and more. This training will give you resources and foundational knowledge that is critical for both you and your supervises. Session will be recorded and posted here once video has been processed for those who are unable to attend at the time of the event. Join Zoom Meeting https://cuboulder.zoom.us/j/92486704095 Meeting ID: 924 8670 4095 One tap mobile +12532158782,,92486704095# US (Tacoma) +13462487799,,92486704095# US (Houston) DateMonday, February 28, 2022 10:00 am Host
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2022-02-28 Atmospheric Chemistry Program Seminar
Atmospheric Chemistry Program SeminarReduction of Iodate in aqueous organic and inorganic thin films Margarita Reza, ANYL 3rd year, "Iodine species are known to catalytically destroy ozone, and in the case of Iodic acid (HIO3), efficiently forms particles. Iodic acid is a source of particulate iodate (IO3-); this has been detected in aged stratospheric air alongside gas-phase IO radical, suggesting the existence of recycling mechanisms reducing IO3- to form volatile iodine species. The reduction of iodate is explored through a series of photochemical coated wall flow tube (CWFT) experiments. A quartz glass tube was coated with an aqueous solution containing sodium iodate in a matrix (i.e., either ammonium bisulfate (ABS), 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CA), or Fe(III) citrate (Fe-Cit) and CA) at a concentration ratio iodate:matrix = 1:100. A thin aqueous film forms on the inside walls by passing a stream of humidified air through the CWFT (~80% RH). For each film, the formation of gaseous iodine (I2) was followed in three types of experiments: (1) dark reaction with H2O2 involved flowing H2O2 through the CWFT for several hours in the dark; (2) photochemical experiments involved irradiating the CWFT with visible lights and UVA lights, separately; and (3) dark-aging experiments involved flowing H2O2 through the CWFT for several hours in the dark, followed by irradiation with visible light. The evaporation of gas-phase I2 from the aqueous films was measured by cavity enhanced differential optical absorption spectroscopy (CE-DOAS) coupled to the CWFT. The cleanliness of the materials, cleaning procedures used, and the absence of uncontrolled chromophores reducing iodate, that might be intrinsic to the CWFT setup was confirmed in blank experiments. The I2 released from aged films irradiated with visible light (type 3 experiments) was found to be substantially greater than that from irradiated fresh films (type 2), or fresh films exposed to H2O2 in the dark (type 1). This increase of I2 in H2O2 aged films, independently observed in both inorganic and organic matrices, suggests that a secondary inorganic chromophore is formed from the reaction of iodate with H2O2. A photochemical pathway was discovered in which visible light is sufficient for reducing iodate to I2. This is relevant in the atmosphere because it helps to explain the co-existence of particulate IO3- and gas-phase IO radicals recently observed by aircraft measurements in the stratosphere. Multiphase re-cycling of I2 from particulate IO3- in absence of ultraviolet light further suggests that a catalytic reaction cycle is more active than previously thought, and involves three steps: (1) gas-phase HIO3 formation from I2 photolysis, (2) condensation and dissociation of HIO3 to form IO3-, and (3) IO3- reduction to re-cycle I2. This catalytic reaction cycle destroys O3 by multiphase chemistry, and highlights a possible catalytic role of HIO3 in particle formation. This photochemistry is currently missing in atmospheric models, seems relevant to predictions about the partitioning of iodine between the gas- and particle phases, invigorates particle formation from iodine oxoacids, and seems relevant to better understand iodine’s role in the recovery of the ozone layer." DateMonday, February 28, 2022 12:15 pm Host
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contactanne.handschy@colorado.edu 2022-02-28 |